The Organometallic Chemistry of N-heterocyclic Carbenes

Reeks: Inorganic Chemistry: A Textbook Series

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  • The
  • Organometallic
  • Chemistry
  • of
  • N-heterocyclic
  • Carbenes
  • describes
  • various
  • aspects
  • of
  • N-heterocyclic
  • Carbenes
  • (NHCs)
  • and
  • their
  • transition
  • metal
  • complexes
  • at
  • an
  • entry
  • level
  • suitable
  • for
  • advanced
  • undergraduate
  • students
  • and
  • above.The
  • book
  • starts
  • with
  • a
  • historical
  • overview
  • on
  • the
  • quest
  • for
  • carbenes
  • and
  • their
  • complexes.
  • Subsequently,
  • unique
  • properties,
  • reactivities
  • and
  • nomenclature
  • of
  • the
  • four
  • classical
  • NHCs
  • derived
  • from
  • imidazoline,
  • imidazole,
  • benzimidazole
  • and
  • 1,2,4-triazole
  • are
  • elaborated.
  • General
  • and
  • historically
  • relevant
  • synthetic
  • aspects
  • for
  • NHCs,
  • their
  • precursors
  • and
  • complexes
  • are
  • then
  • explained.
  • The
  • book
  • continues
  • with
  • coverage
  • on
  • the
  • preparation
  • and
  • characteristics
  • of
  • selected
  • NHC
  • complexes
  • containing
  • the
  • most
  • common
  • metals
  • in
  • this
  • area,
  • i.e.
  • Ni,
  • Pd,
  • Pt,
  • Ag,
  • Cu,
  • Au,
  • Ru,
  • Rh
  • and
  • Ir.
  • The
  • book
  • concludes
  • with
  • an
  • overview
  • and
  • outlook
  • on
  • the
  • development
  • of
  • various
  • non-classical
  • NHCs
  • beyond
  • the
  • four
  • classical
  • types.Topics
  • covered
  • include:The
  • Organometallic
  • Chemistry
  • of
  • N-heterocyclic
  • Carbenes
  • is
  • an
  • essential
  • resource
  • for
  • all
  • students
  • and
  • researchers
  • interested
  • in
  • this
  • increasingly
  • important
  • and
  • popular
  • field
  • of research.
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